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We report the suppression of nucleation in the nonphotochemical laser-induced nucleation of supersaturated aqueous potassium chloride solutions when the system pressure is above ambient pressure. The crystal yield at 51.7 bar is reduced to 5% of its value at 1 bar, and the crystal number dependence on pressure fits well to a semiempirical model based on the impurity-heating mechanism and the adiabatic compression of an ideal gas nanobubble. Our results complement recent findings by Barber and Alexander [] using high-speed imaging of bubbles preceding the observation of cesium chloride crystals. Together, these two studies provide compelling evidence for the impurity-heating mechanism.more » « lessFree, publicly-accessible full text available October 1, 2026
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Shah, Neel J.; Shalaby, Marwan; He, Lilin; Wang, Xin; Deslandes, David; Garetz, Bruce A.; Balsara, Nitash P. (, ACS Macro Letters)
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Sharrock, Chappel J.; Cho, Ja Eon; Wang, Xin; Li, Xiuhong; Loo, Whitney; Balsara, Nitash P.; Garetz, Bruce A. (, Macromolecules)
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Gao, Kevin W.; Loo, Whitney S.; Snyder, Rachel L.; Abel, Brooks A.; Choo, Youngwoo; Lee, Andrew; Teixeira, Susana C.; Garetz, Bruce A.; Coates, Geoffrey W.; Balsara, Nitash P. (, Macromolecules)null (Ed.)
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